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- A

- B

- ✓

- D

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$\begin{matrix}
\underset{X}{\mathop{H}}{{O}_{2}}C-C{{H}_{2}}-CH-C{{O}_{2}}\underset{Z}{\mathop{H}}\, \\
\,\,\,\,\,\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,+N{{H}_{3}} \\
\end{matrix}$
The isoelectric point for the amino acid is

The half-life period is independent of the concentration of zinc at constant $pH$. For the constant concentration of $Zn$, the rate becomes $100$ times when $pH$ is decreased from $3\, to\, 2$. Identify the correct statements $(pH = -\log [H^{+}])$
$(A)$ $\frac{{dx}}{{dt}}\, = k{[Zn]^0}{[{H^ + }]^2}$
$(B)$ $\frac{{dx}}{{dt}}\, = k{[Zn]}{[{H^ + }]^2}$
$(C)$ Rate is not affected if the concentraton of zinc is made four times and that of $H^+$ ion is halved.
$(D)$ Rate becomes four times if the concentration of $H^+$ ion is doubled at constant $Zn$ concentration