MCQ
Hofmann's hypobromite reaction affords a method of
- APreparing a tertiary amine
- BPreparing a mixture of amines
- ✓Stepping down a series
- DStepping up a series
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The following data are observed
| $[X_2]$ | $[Y_2]$ | Rate of appearance of $XY$ ($M/sec$) |
| $0.1$ | $0.1$ | $5 × 10^{-6}$ |
| $0.2$ | $0.1$ | $10^{-5}$ |
| $0.2$ | $0.2$ | $4 × 10^{-5}$ |
Rate constant of reaction will (in $M^{1-n}\,sec^{-1}$) where $'n'$ is order of reaction
| List$-I$ | List$-II$ |
| $(a)$ $\left[ Co \left( NH _{3}\right)_{6}\right]\left[ Cr ( CN )_{6}\right]$ |
$(i)$ Linkage isomerism |
| $(b)$ $\left[ Co \left( NH _{3}\right)_{3}\left( NO _{2}\right)_{3}\right]$ |
$(ii)$Solvate isomerism |
| $(c)$ $\left[ Cr \left( H _{2} O \right)_{6}\right] Cl _{3}$ |
$(iii)$ Co-ordination isomerism |
| $(c)$ $cis-[CrCl$ $\left._{2}(\text { ox })_{2}\right]^{3-}$ | $(iv)$ Optical isomerism |
Choose the correct answer from the options given below:
$\left[\right.$ Given $\left.\mathrm{R}=8.314 \,\mathrm{JK}^{-1} \,\mathrm{~mol}^{-1}\right]$