$\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,|| \\
Ph-CH-C-H+EtOH\xrightarrow[\Delta ]{HCl}Ph-CH-C-O-Et+{{H}_{2}}O \\
\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\,\,\,OH\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}$
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|
List-$I$ Reaction |
List-$II$ Type of redox reaction |
| $(A)$ $\mathrm{N}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{NO}_{(\mathrm{g})}$ | $(I)$ Decomposition |
| $(B)$ $\begin{aligned} & 2 \mathrm{~Pb}\left(\mathrm{NO}_3\right)_{2(\mathrm{~s})} \rightarrow 2 \mathrm{PbO}_{(\mathrm{s})}+4 \mathrm{NO}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})}\end{aligned}$ | $(II)$ Displacement |
| $(C)$ $\begin{aligned} 2 \mathrm{Na}_{(\mathrm{s})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow 2 \mathrm{NaOH}_{(\mathrm{aq} .)}+\mathrm{H}_{2(\mathrm{~g})}\end{aligned}$ | $(III)$ Disproportionation |
| $(D)$ $\begin{aligned} 2 \mathrm{NO}_{2(\mathrm{~g})}+2-\mathrm{OH}_{(\mathrm{aq})} \rightarrow \mathrm{NO}_{2(\mathrm{aq} .)}^{-}+\mathrm{NO}_{3(\mathrm{qq} .)}^{-}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}\end{aligned}$ | $(IV)$ Combination |
Choose the correct answer from the options given below:
$3 \mathrm{PbCl}_2+2\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \rightarrow \mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2+6 \mathrm{NH}_4 \mathrm{Cl}$
If $72 \mathrm{mmol}$ of $\mathrm{PbCl}_2$ is mixed with $50 \mathrm{mmol}$ of$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4$, then amount of $\mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2$ formed is......... mmol. (nearest integer)