MCQ
Which of the following is non-aromatic ?
- APyrrole
- BThiophene
- CFuran
- ✓Pyran
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Assertion $(A)$ $:$ When Cu $(II)$ and sulphide ions are mixed, they react together extremely quickly to give a solid.
Reason $(R)$ $:$ The equilibrium constant of $Cu ^{2+}( aq )+ S ^{2-}( aq ) \rightleftharpoons \operatorname{CuS}( s )$ is high because the solubility product is low.
$Mn^{2+} +2e- \rightarrow Mn;\, E^o = -1.18\,V$
$2(Mn^{3+} +e^- \rightarrow Mn^{2+} )\,;\,E^o=+1.51\,V$
The $E^o$ for $3Mn^{2+} \rightarrow Mn+ 2Mn^{3+}$ will be :
$Zn\,(s)\,\, + \,\,C{u^{2 + }}\,(aq)\, \rightleftharpoons \,Z{n^{2 + \,}}\,(aq)\, + Cu\,(s)$
At $300\,K$ is approximately $(R = 8 \,JK^{-1}\,mol^{-1},\, F = 96000\,C\,mol^{-1})$