- APresence of low oxidation state of copper.
- BCompletely filled d-level in Cu(I).
- CDiamagnetic nature of the compound.
- DHigh polarizability of Cu(I) ion.
Explanation:
In copper (I) ion there are no vacant d orbitals as it is diamagnetic. Copper(I) ion being less charged has small ligand field effect and the transition is in the infrared region in which no color is perceived by human eye.
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(Rounded-off to the nearest integer)
$(i)$ ${A_2} \to A + A$ (fast)
$(ii)$ $A + {B_2} \to AB + B$ (slow)
$(iii)$ $A + B \to $ (fast)
$(W)$ Red ppt. $\xrightarrow{{dil.\,\,HCl}}$ $(Y)$ white ppt.
$(U)$ $\mathop {\xrightarrow{{NaOH}}}\limits_\Delta $ $(Z)$ gas (gives white fumes with $HCl$ ) ?
sublimes on heating
Identify $(T)$ to $(Z).$
$[A]$ The activation energy of the reaction is unaffected by the value of the steric factor
$[B]$ Experimentally determined value of frequency factor is higher than that predicted by Arrhenius equation
$[C]$ Since $P=4.5$, the reaction will not proceed unless an effective catalyst is used
$[D]$ The value of frequency factor predicted by Arrhenius equation is higher than that determined experimentally
$\begin{array}{*{20}{c}}
{{\,\,R_1}} \\
| \\
{R - C - X} \\
| \\
{{\,\,R_2}}
\end{array}\xrightarrow{{HOH}}\begin{array}{*{20}{c}}
{{\,\,R_1}\,\,\,\,} \\
{|\,\,\,\,} \\
{R - C - OH} \\
{|\,\,\,\,\,} \\
{{\,\,R_2}\,\,\,\,}
\end{array}$
Which substrate will give maximum racemisation ?