MCQ
Oxidation number of $N$ in ammonium nitrate is
  • A
    $+3$
  • B
    $-3$
  • $-3$ and $+5$
  • D
    $+5$

Answer

Correct option: C.
$-3$ and $+5$
c
Ammonium nitrate $\longrightarrow \mathrm{NH}_{4} \mathrm{NO}_{3}$

which can be written as $\mathrm{NH}_{4}^{+} \mathrm{NO}_{3}^{-}$ For $\mathrm{NH}_{4}^{+}$

Let oxidation state of $\mathrm{N}=\mathrm{x}$

we know that oxidation state of $\mathrm{H}=+1$

Sum of total oxidation state of all atoms $=$ Overall charge on the compound. $x+4 \times(1)=1$

$\mathrm{x}=-3$

Let oxidation state of $\mathrm{N}$ in $\mathrm{N} \mathrm{O}_{3}^{-}=\mathrm{y}$, we know that oxidation state of $\mathrm{O}=-2$

Applying above formula $y+3 \times(-2)=1$

$y=+5$

Oxidation state of $\mathrm{N}$ in $\mathrm{NH}_{4} \mathrm{N} \mathrm{O}_{3}=-3,+5$

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