- A$\text{IIA}$ and $\text{VA}$
- B$\text{IIIA}$ and $\text{VIA}$
- C$\text{IIA}$ and $\text{VIA}$
- ✓$\text{IA}$ and $\text{VIIA}$
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Codes: $ \quad P \quad Q \quad R \quad S $
$(a)$ $H _{2} C _{2} O _{4} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{-}$
$(b)$ $HC _{2} O _{4}^{-} \rightleftharpoons H ^{+}+ HC _{2} O _{4}^{2-}$
$(c)$ $H _{2} C _{2} O _{4} \rightleftharpoons 2 H ^{+}+ C _{2} O _{4}^{2-}$
The relationship between $K_{a_{1}}, K_{ a _{2}}$ and $K_{ a _{3}}$ is given as
List $-I$
$(A){\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {C_6}{H_6} + CO + HCl\,\xrightarrow{{AlC{l_3}}}\,{C_6}{H_5}CHO$
$(B){\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {C_6}{H_5} + C{H_3}$ $\xrightarrow{{Cr{O_2}C{l_2}}}\,{C_6}{H_5}CHO$
$(C){\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {C_6}{H_5}C{H_2}Br\, + \,C{H_3}Br$ $\xrightarrow{{Na/ether}}\,{C_6}{H_5}C{H_2}C{H_3}$
$(D){\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {C_6}{H_6}\, + \,{(C{H_3})_2}C = C{H_2}$ $\xrightarrow{{{H_2}S{O_4}}}\,{C_6}{H_5}C{(C{H_3})_3}$
List $-II$
$(a)$ Friedel-Crafts reaction
$(b)$ Wurtz-Fitting reaction
$(c)$ Gattermann-Koch Aldehyde synthesis
$(d)$ Etard’s reaction