MCQ
What changes does not occur when $K_2Cr_2O_7$ react with $H_2O_2$ solution
  • A
    Orange colour of solution turns blue
  • $O.S$. of $Cr$ atom decreases
  • C
    $O.S.$ of $Cr$ atom remains constant
  • D
    None of these

Answer

Correct option: B.
$O.S$. of $Cr$ atom decreases
b

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$1.$ $2 \mathrm{Ag}^{+}+\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{Ag}(\mathrm{s})+\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7+2 \mathrm{H}^{+}$

Find $\ln \mathrm{K}$ of this reaction.

$(A)$ $66.13$  $(B)$ $58.38$  $(C)$ $28.30$  $(D)$ $46.29$

$2.$ When ammonia is added to the solution, $\mathrm{pH}$ is raised to $11$ . Which half-cell reaction is affected by $\mathrm{pH}$ and by how much?

(A) $E_{\text {oxd }}$ will increase by a factor of $0.65$ from $E_{\text {oxd }}^{\circ}$

(B) $E_{\text {oxd }}$ will decrease by a factor of $0.65$ from $E_{\mathrm{cod}}^{\prime}$

(C) $\mathrm{E}_{\text {red }}$ will increase by a factor of $0.65$ from $\mathrm{E}_{\text {rod }}^{\circ}$

(D) $E_{\text {red }}$ will decrease by a factor of $0.65$ from $E_{\text {rod }}^2$

$3.$   Ammonia is always is added in this reaction. Which of the following must be incorrect?

$(A)$ $\mathrm{NH}_3$ combines with $\mathrm{Ag}^{+}$to form a complex.

$(B)$ $\mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}$is a stronger oxidising reagent than $\mathrm{Ag}^{+}$.

$(C)$ In absence of $\mathrm{NH}_3$ silver salt of gluconic acid is formed.

$(D)$ $\mathrm{NH}_3$ has affected the standard reduction potential of glucose/gluconic acid electrode.

Give the answer question $1,2$ and $3.$