- A$MnO _2^{-}$
- B$MnO _4^{-}$
- ✓$MnO _4^2$
- D$Mn ^{2+}$
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${O_3}(g)\, + \,C{l^ * }(g)\, \to \,{O_2}(g) + Cl{O^ * }(g)$ ..... $(i)$ $[{K_i} = 5.2 \times {10^9}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
$Cl{O^ * }(g) + {O^ * }(g)\, \to \,{O_2}(g) + \,C{l^ * }(g)$ ..... $(ii)$ $[{K_{ii}} = 2.6 \times {10^{10}}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$
The closest rate constant for the overall reaction
${O_3}(g){\mkern 1mu} + {\mkern 1mu} {O^*}(g){\mkern 1mu} \to {\mkern 1mu} 2{O_2}(g)$ is ........... $L\,\,mo{l^{ - 1}}\,{s^{ - 1}}$
Statement I : $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ is a homoleptic complex whereas $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$is a heteroleptic complex.
Statement II : Complex $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ has only one kind of ligands but $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$has more than one kind of ligands.
In the light of the above statements, choose the correct answer from the options given below.