Question
What is quantum mechanics? Explain the Schrodinger wave equation for hydrogen.

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At 1127 K and 1 atm pressure, a gaseous mixture of CO and $CO _2$ in equilibrium with solid carbon has $90.55 \% CO$ by mass
$C ( s )+ CO _2(g) \rightleftharpoons 2 CO ( g )$
Calculate $K_c$ for this reaction at the above temperature.
Write the general outer electronic configuration of s-, p-, d- and f- block elements.
Structures of molecules of two compounds are given below:

  1. Which of the two compounds will have intermolccular hydrogen bonding and which compound is expected to show intramolecular hydrogen bonding?
  2. The melting point of a compound depends on. among other things, the extent of hydrogen bonding. On this basis explain which of the above two compounds will show higher melting point.
  3. Solubility of compounds in water depends on power to form hydrogen bonds with water. Which of the above compounds will form hydrogen bond with water easily and be more soluble in it?
Match the species in Column I with the type of hybrid orbitals in Column II.
 
Column I
 
Column II
i.
Tetrahedral
a.
sp2
ii.
Trigonal
b.
sp
iii.
Linear
c.
sp3
Assuming complete dissociation, calculate the pH of the following solutions : (a) 0.003 M HCl (b) 0.005 M NaOH (c) 0.002 M HBr (d) 0.002 M KOH
Give a brief description of the principles of the following techniques taking an example in each case.
Chromatography.
How do you count for the following observations?
Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.
The ionization constant of acetic acid is 1.74 × 10–5. Calculate the degree of dissociation of acetic acid in its 0.05M solution. Calculate the concentration of acetate ion in the solution and its pH.
At 1127 K and 1 atmosphere pressure, a gaseous mixture of CO and $CO _2$ in equilibrium with solid carbon has 90.55\% CO by mass.
$
C(s)+CO_2(g) \rightleftharpoons 2 CO(g)
$
Calculate $K _{ c }$ for the reaction at the above temperature.
  1. A sample of salt has the following percentage composition

Fe = 36.76%, S = 21.11 % and O = 42.14%

Calculate the empirical formula of the compound

  1. What happens if the compound is heated? Write the balanced chemical equation.