Question
What is spectrochemical series? Explain the difference between a weak field ligand and a strong field ligand.
| Weak field ligand | Strong field ligand | |
| 1. | They are formed when the crystal field stabilisation energy (Δ0) in octahedral complexes is less than the energy required for an electron pairing in a single orbital (p). | They are formed when the crystal field stabilisation energy (Δ0) is greater than the p. |
| 2. | They are also called high spin complexes. | They are called low spin complexes. |
| 3. | They are mostly paramagnetic in nature complex. | They are mostly diamagnetic or less paramagnetic than weak field. |
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| | Column I (Property) | | Column II (Metal) |
| (i) | An element which can show +8 oxidation state | (a) | Mn |
| (ii) | 3d block element that can show upto +7 oxidation state | (b) | Cr |
| (iii) | 3d block element with highest melting point | (c) | Os |
| (d) | Fe |