- A${[Zn{(CN)_4}]^{2 - }}$
- ✓${[Cr{({H_2}O)_6}]^{3 + }}$
- C${[Cu{(CN)_4}]^{2 - }}$
- D${[Ni{(N{H_3})_4}]^{2 + }}$
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Which conformer of above compound is most stable (consider conformer across $(C_2 -C_3)$
$\Delta {H_{{\rm{System}}}} = 2000\ kJ/mol$
$T = 400\ K$
Find out value of $\Delta {S_{{\rm{System}}}}$..........$ kJ/mol-K$
$C{{H}_{3}}-\underset{C{{H}_{3}}}{\mathop{\underset{|\,\,\,\,\,}{\mathop{\overset{OH}{\mathop{\overset{|\,\,\,\,}{\mathop{C-}}\,}}\,}}\,}}\,C{{H}_{2}}-\underset{C{{H}_{3}}\,}{\mathop{\underset{|\,\,\,\,\,\,\,}{\mathop{CH-}}\,}}\,C{{H}_{3}}$
[$A$] The work done on the gas is maximum when it is compressed irreversibly from ( $\mathrm{p}_2, \mathrm{~V}_2$ ) to ( $\mathrm{p}_1, \mathrm{~V}_1$ ) against constant pressure $\mathrm{pl}_1$
[$B$] The work done by the gas is less when it is expanded reversibly from $V_1$ to $V_2$ under adiabatic conditions as compared to that when expanded reversibly from $V_1$ to $V_2$ under isothermal conditions
[$C$] The change in internal energy of the gas is ($i$) zero, if it is expanded reversibly with $T_1=T_2$, and ($ii$) positive, if it is expanded reversibly under adiabatic conditions with $T_1 \neq T_2$
[$D$] If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic