- A$NH_4NO_2$
- B$NH_4NO_3$
- C$NaN_3$
- ✓Both $(A)$ and $(C)$
$(B)$ $\mathrm{NH}_{4} \mathrm{NO}_{3} \stackrel{\Delta}{\longrightarrow} \mathrm{N}_{2} \mathrm{O}+2 \mathrm{H}_{2} \mathrm{O}$
$(C)$ $2 \mathrm{NaN}_{3} \stackrel{\Delta}{\longrightarrow} 3 \mathrm{N}_{2}+2 \mathrm{Na}$
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[Given, atomic number: $Mn =25, Fe =26, Co =27$; en $= H _2 NCH _2 CH _2 NH _2$ ]
$2NO(g) + O_2(g) \rightleftharpoons 2NO_2(g)$
The standard free energy of formation of $NO(g)$ is $86.6\, kJ/mol$ at $298 \,K.$ What is the standard free energy of formation of $NO_2(g)$ at $298\, K$ ? ($K_p = 1.6 \times 10^{12})$
$\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
HOC{{H}_{2}}C{{H}_{2}}CHC{{H}_{2}}C{{H}_{2}}COH \\
\end{matrix}$ $\xrightarrow[tetrahydro\,\,futan ]{(x)\,\,C{{H}_{3}}Li}$ $\xrightarrow[{{H}_{2}}]{N{{H}_{4}}Cl}$ $\underset{Compound\,\,\,A\,\,63\,\%}{\mathop{\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\, \\
\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
HOC{{H}_{2}}C{{H}_{2}}CHC{{H}_{2}}C{{H}_{2}}-C-C{{H}_{3}} \\
\end{matrix}}}\,$ $\underset{37\,\%}{\mathop{+\,\,Compound\,\,(B)}}\,$
Value of $(x)$ in above reaction is