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$\mathrm{Eu}, \mathrm{Cm}, \mathrm{Er}, \mathrm{Tb}, \mathrm{Yb}$ and $\mathrm{Lu}$
$\underset{({{C}_{2}}{{H}_{6}}O)}{\mathop{X}}\,\,\xrightarrow[573\,\,K]{Cu}$ $A$ $\xrightarrow[^{-}OH\,,\,\Delta ]{{{[Ag{{(N{{H}_{3}})}_{2}}]}^{+}}}$ Silver mirror
$A\,\xrightarrow{^{-}OH\,,\,\Delta }Y$
$A\,\xrightarrow{N{{H}_{2}}NHCON{{H}_{2}}}Z$
$\,\,\begin{array}{*{20}{c}}
{C{H_3} - C - H\,} \\
\,\,\,\,{||} \\
\,\,\,\,{O\,}
\end{array} + \,C{H_3} - C{H_2} - CHO\xrightarrow{{\overline O H/{H_2}O}}$
Product in above reaction is
$\begin{align}
\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,|| \\
H-O-C-C- \\
\end{matrix}\begin{matrix}
O\,\, \\
||\,\,\, \\
C{{H}_{2}}-C-O-H \\
\end{matrix} \\
p{{K}_{a}}=2.2\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,p{{K}_{a}}=3.98 \\
\end{align}$