1. Solution and colligative properties — Chemistry STD 12 Science — Question

Where $A$ is $PCl^+_4$ while $B$ is $PCl^-_ 6$

Which of the following statement is INCORRECT :

$(I)$ $B$ to $A$ involvement of number of $d-$orbital in hybridization increases

$(II)$ $A$ to $B$ precentage of $p-$character in $P-Cl$ bond increases

$(III) $ Number of covalent bond in $A$ and $B$ are same

$(IV)$ $B$ is product of Lewis acid-base interaction which is associated with super octet molecule only

${\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}, \quad\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}, \quad\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},}$

${\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}}$

[Given atomic numbers: $\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26$,

$\mathrm{Ni}=28, \mathrm{Cu}=29]$