$C{{H}_{3}}-N{{H}_{2}}+2HONO\,\to C{{H}_{3}}-ONO+{{N}_{2}}+2{{H}_{2}}O$
while dimethylamine and trimethyl amine form insoluble compound with hinsberg reagent and $KOH$.
${{R}_{2}}NH\,+\,{{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl\,\xrightarrow{O{{H}^{-}}}$ ${{C}_{6}}{{H}_{5}}S{{O}_{2}}N{{R}_{2}}$
${{R}_{3}}N\,+\,{{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl\,\xrightarrow{O{{H}^{-}}}\underset{insoluble}{\mathop{{{R}_{3}}N}}\,$
Azo dyes are not formed by secondary amines.
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$\operatorname{cis}-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-},\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$
$\operatorname{cis}-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { cis }-\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}$
$\text {trans }-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { trans }-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-}$