MCQ
Which one has the highest boiling point
  • A
    $0.1N\,N{a_2}S{O_4}$
  • B
    $0.1N\,MgS{O_4}$
  • $0.1M\,A{l_2}{(S{O_4})_3}$
  • D
    $0.1M\,BaS{O_4}$

Answer

Correct option: C.
$0.1M\,A{l_2}{(S{O_4})_3}$
c
(c)$A{l_2}{(S{O_4})_3}$ gives maximum ion hence it will show highest boiling point.

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$\underset{(A)}{\mathop{\begin{matrix}
   \,\,\,\,\,Ph\,\,\,\,C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,|\,\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,|\,\,\,  \\
   \,OH\,\,\,OH  \\
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   \,\,\,\,Ph\,\,\,Et  \\
   \,\,|\,\,\,\,\,\,\,\,\,|  \\
   Ph-C-C-Et  \\
   \,\,|\,\,\,\,\,\,\,\,\,|  \\
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   Ph\,\,\,\,\,O\,  \\
   |\,\,\,\,\,\,\,\,||\,\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\,  \\
\end{matrix}$                                $(q)$ $\begin{matrix}
   \,Ph\,\,\,\,\,O\,  \\
   \,\,|\,\,\,\,\,\,\,\,||  \\
   Ph-C-C-Et  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
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\end{matrix}$

$(r)$ $\begin{matrix}
   \,Ph\,\,\,\,\,O\,  \\
   |\,\,\,\,\,\,\,\,\,\,||\,  \\
   Ph-C-C-C{{H}_{3}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   Et\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}$                             $(s)$ $\begin{matrix}
   \,\,\,Ph\,\,\,\,\,O\,  \\
   \,\,|\,\,\,\,\,\,\,\,||  \\
   Ph-C-C-Et  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,  \\
\end{matrix}$

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