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Answer the following questions: Describe the preparation of potassium permanganate from pyrolusite ore. Write balanced chemical equation for one reaction to show the oxidizing nature of potassium permanganate.
Describe the standard hydrogen electrode with diagram.
Explain different types of isomerism in amines.
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  3. Mention the two products of glycolysis.
Derive the equation required for finding the activation energy.
Write two applications of electrochemical series.
  1. Complete the following chemical equations for reactions:
i. $\text{MnO}_{4(aq)}^{-}+\text{S}_{2}\text{O}_{3(aq)}^{2-}+\text{H}_{2}\text{O}_{(l)}\rightarrow$
ii. $\text{Cr}_{2}\text{O}^{-}_{7(aq)}+\text{H}_{2}\text{S}_{(g)}+\text{H}^{+}_{(aq)}\rightarrow$
  1. Give an explanation for each of the following, observations:
  1. The gradual decrease in size $($actinoid contraction$)$ from element to element is greater among the .actinoids than that among the lanthanoids $($lanthanoid contraction$).$
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Decinormal solution of NaCl developed an osmotic pressure of 4.6 atm at 300 K. Calculate the degree of dissociation.
Complete the following reactions :
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(ii) $C _6 H _5 N_2 Cl + H _3 PO _2+ H _2 O \longrightarrow$
(iii) $C _6 H _5 NH _2+ H _2 SO _4$ (conc.) ⟶
(iv) $C _6 H _5 N_2 Cl + C _2 H _5 OH \longrightarrow$
(v) $C _6 H _5 NH _2+ Br _2(a q) \longrightarrow$
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
i. $\ce{k \left[ Cr \left( H _2 O \right)_2\left( C _2 O _4\right)_2\right]}$
ii. $\ce{\left[ Co ( en )_3\right] Cl _3}$
iii. $\ce{\left[ Co \left( NH _3\right)_5\left( NO _2\right)\left( NO _3\right)_2\right]}$
iv. $\ce{ \left [ Pt ( NH _3) ( H _2 O ) Cl _2\right].}$