Question
What is spectrochemical series? Explain the difference between a weak field ligand and a strong field ligand.
| Weak field ligand | Strong field ligand | |
| 1. | They are formed when the crystal field stabilisation energy (Δ0) in octahedral complexes is less than the energy required for an electron pairing in a single orbital (p). | They are formed when the crystal field stabilisation energy (Δ0) is greater than the p. |
| 2. | They are also called high spin complexes. | They are called low spin complexes. |
| 3. | They are mostly paramagnetic in nature complex. | They are mostly diamagnetic or less paramagnetic than weak field. |
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2 Fe3+ (aq) + 2 I- (aq) $\longrightarrow$ 2 Fe2+ (aq) + I2 (s)
has $\text{E}^0_{\text{cell}}$ = 0·236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol-1)