MCQ
When ethyl alcohol reacts with nitric acid, it forms:
- ANitromethane
- BNitroethane
- CEthyl nitrate
- DDiethyl ether
Explanation:
CH3–CH2–OH + HNO3 → C2H5NO3 + H2O
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| Run | $[A]/mol\,L^{-1}$ | $[B]/mol\,L^{-1}$ | Initial rate of formation of $D/mol\,L^{-1}\,min^{-1}$ |
| $I.$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
| $II.$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
| $III.$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
| $IV.$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Based on the above data which one of the following is correct?
$(a)$ Lewis acidity order : $SiF_4 < SiC_{4} < SiBr_4 < Sil_4$
$(b)$ Melting point : $NH_3 > SbH_3 > AsH_3 > PH_3$
$(c)$ Boiling point : $NH_3 > SbH_3 > AsH_3 > PH_3$
$(d)$ Dipole moment order : $NH_3 > SbH_3 > AsH_3 > PH_3$
${\left( {I} \right)}$ ${{C_6}{H_5}COC{H_3}}$
${\left( {II} \right)}$ ${C{H_3}COC{H_3}}$
${\left( {III} \right)}$ ${C{H_3} - CHO}$
$Pb \left( NO _{3}\right)_{2} \stackrel{673 K }{\longrightarrow} A + PbO + O _{2}$
$A \stackrel{\text { Dimerise }}{\longrightarrow} B$